Navigation Links
Sounding out Congo Red

Brightly colored dyes such as the shimmering Congo Red commonly used in silk clothing manufacture are notoriously difficult to dispose of in an environmentally benign way.

Congo Red is an azo dye, it is toxic to many organisms and is a suspected carcinogen and mutagen. To give it its full name it is the disodium salt of 3,3'-(1E,1'E)-biphenyl-4,4'-diylbis(diazene-2,1-diyl)bis(4-aminonaphthalene-1-sulfonate). It is a benzidine-based anionic disazo dye. Benzidine and Congo Red are, however, banned in many countries because of health concerns. But, it is still widely used in several countries.

Apparently it is used not only to dye silk a gorgeous red, but cleverly adds a second shimmering color and rending the red silk shot through with yellow. It also represents a significant effluent problem along with related dyes from textiles, printing and dyeing, paper, rubber, and plastic industries. Its structural stability makes it highly resistant to biodegradation, and obviously its bright color and toxicity are entirely undesirable in the environment.

Writing in the International Journal of Environment and Waste Management (2008, 2, 309-319), Srinivas Sistla and Suresh Chintalapati, from Hyderabad, India, explain a new approach to degrading Congo Red based on ultrasound.

The researchers point out that advanced oxidation processes (AOP) are currently being developed for remediation of contaminated effluent because they generate no hazardous sludge. Oxidative degradation is based on free radical attack using powerful oxidants. However, Sistla and Chintalapati suggest that sonolysis, break down of an organic compound with ultrasound, has so far been investigated only rarely as an alternative remediation technology. Under well-established 'extreme' conditions, materials irradiated with sound at frequencies around 50 kHz are essentially ripped apart by the formation of free radicals, say the researchers. Carbon dioxide and water are the usual products, although with the case of azo dyes, nitrogen would also feature in the byproducts.

Sonication of Congo Red in the aqueous phase with 50 kHz ultrasound transforms it into a milieu of less toxic intermediates that can then be broken down still further by conventional industrial waste water biodegradation treatment. As a proof of principle, the researchers suggest that the combination of ultrasound and biodegradation could allow the color to be removed from dye-contaminated industrial effluent effectively and the toxicity reduced to negligible levels. "The results obtained from this study revealed the ability of ultrasonic irradiation to transform the aromatic inhibitory compounds to less toxic intermediates, which can be further utilized in aerobic/anaerobic oxidation," the researchers conclude.


Contact: Srinivas Sistla
Inderscience Publishers

Related medicine news :

1. Leverage Lifes Homework Hotline Is a Resounding Success!
2. Lucian Leape Institute First Roundtable: A Resounding Success
3. U.S. Food Safety: The Import Alarm Keeps Sounding
4. NBA Legend Dikembe Mutombo Joins Opportunity International Board of Advisors; Opens Doors in Democratic Republic of Congo
5. Women for Women International Congolese Country Director, Christine Karumba, Speaks Out About the Rape Epidemic in the Democratic Republic of the Congo.
Post Your Comments:
(Date:11/27/2015)... ... , ... Indosoft Inc., developer and distributor of the world-class ... (Long Term Support) into its Q-Suite 5.10 product line. , Making the change ... version of Asterisk that will receive not only security fixes, but feature and ...
(Date:11/26/2015)... ... November 26, 2015 , ... ... eReferral system for diagnostic imaging in the Waterloo region. Using the Ocean Platform, ... Medicine tests directly from their electronic medical record (EMR) without the need for ...
(Date:11/26/2015)... ... , ... Jobs in hospital medical laboratories and in the imaging field lead ... Aureus Medical Group . These fields, as well as travel nursing, ... healthcare jobs through the company’s website, , The leading healthcare staffing ...
(Date:11/26/2015)... ... 26, 2015 , ... Pixel Film Studios brings Final Cut ... Vintage. This newly styled ProTrailer pack comes with 30 all-new vintage-inspired designs, with ... users limitless opportunities to stylize and create designs quickly and easily, all within ...
(Date:11/25/2015)... ... November 25, 2015 , ... Additional breast ... found on mammography, according to a study published online in the journal Radiology. ... on mammography may necessitate a change in treatment. , Breast MRI is the ...
Breaking Medicine News(10 mins):
(Date:11/26/2015)... DUBLIN , November 26, 2015 /PRNewswire/ ... the addition of the "Radioimmunoassay Market ... User (Hospital, Pharmaceutical Industry, Academics, Clinical Diagnostic ... - Global Forecast to 2020" report ... ) has announced the addition of the ...
(Date:11/25/2015)... , Nov. 25, 2015 ... addition of the "Global Brain Monitoring ... offering. --> ) has ... Brain Monitoring Devices Market 2015-2019" report ... and Markets ( ) has announced ...
(Date:11/25/2015)... 2015  Amgen (NASDAQ: AMGN ) today announced ... the United States (U.S.) Food ... candidate to Humira ® (adalimumab). Amgen believes this ... the FDA and represents Amgen,s first BLA submission using ... , M.D., executive vice president of Research and Development ...
Breaking Medicine Technology: