Brightly colored dyes such as the shimmering Congo Red commonly used in silk clothing manufacture are notoriously difficult to dispose of in an environmentally benign way.
Congo Red is an azo dye, it is toxic to many organisms and is a suspected carcinogen and mutagen. To give it its full name it is the disodium salt of 3,3'-(1E,1'E)-biphenyl-4,4'-diylbis(diazene-2,1-diyl)bis(4-aminonaphthalene-1-sulfonate). It is a benzidine-based anionic disazo dye. Benzidine and Congo Red are, however, banned in many countries because of health concerns. But, it is still widely used in several countries.
Apparently it is used not only to dye silk a gorgeous red, but cleverly adds a second shimmering color and rending the red silk shot through with yellow. It also represents a significant effluent problem along with related dyes from textiles, printing and dyeing, paper, rubber, and plastic industries. Its structural stability makes it highly resistant to biodegradation, and obviously its bright color and toxicity are entirely undesirable in the environment.
Writing in the International Journal of Environment and Waste Management (2008, 2, 309-319), Srinivas Sistla and Suresh Chintalapati, from Hyderabad, India, explain a new approach to degrading Congo Red based on ultrasound.
The researchers point out that advanced oxidation processes (AOP) are currently being developed for remediation of contaminated effluent because they generate no hazardous sludge. Oxidative degradation is based on free radical attack using powerful oxidants. However, Sistla and Chintalapati suggest that sonolysis, break down of an organic compound with ultrasound, has so far been investigated only rarely as an alternative remediation technology. Under well-established 'extreme' conditions, materials irradiated with sound at frequencies around 50 kHz are essentially ripped apart by the formation of free radicals, say the researchers. Carbon dioxide and water are the u
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