Navigation Links
Photoluminescence Spectroscopy of Quantum Dots, monitored by the Spex FluoroMax


The optical properties of quantum dots (QDs) have potential applications in optoelectronics, biosensing and biolabeling, memory devices, and sources of laser light. For example, alloyed CdSeTe QDs are shown herein to possess a nonlinear change in their photoluminescence spectra, correlated to size and composition, as monitored by the versatile Spex FluoroMax spectrofluorometer. The QDs' emission wavelength can be as high as 850 nm, which may be useful for imaging deeper into living tissue than visible light can penetrate.


Experiment
The procedure for synthesizing alloyed CdSeTe QDs (2.7-8.6 nm diameter) from pure CdO, Se shot, and Te powder in tri-n-octylphosphine oxide and hexadecylamine is given elsewhere (1). The nanoparticles were purified by precipitation and centrifugation, then stored at room temperature. Absorption spectra were monitored on a Shimadzu spectrophotometer (slit = 1.0 nm). Fendler, et al's method (2) for finding the absorption onset and band-gap energies was used with the absorption data. Photoluminescence spectra were recorded using a Spex FluoroMax spectrofluorometer. The emission spectra were performed with an excitation wavelength of 475 nm and slit-widths of 2.0 nm. All spectra were corrected for the detector's wavelength-dependent response.


Results
QDs in layered solutions (CCL4 below; water, above) under ambient and UV light are shown in Figure 1. QDs coated with tri-n-octyl phosphine oxide remain in the organic layer, while those coated with m ercaptoacetic acid are in the aqueous layer.

Figure 1. QDs coated with tri-n-octyl phosphine oxide (tri) and mercaptoacetic acid (mer) under (a) ambient and (b) ultraviolet illumination. The upper layer is water; the lower layer is CCL4.


A range of alloyed QDs were examined via absorption and photoluminescence spectroscopy (Figure 2). Comparative literature values for bulk alloys are included (3). The data reveal resolved electronic transitions, plus fluorescence emission at the band-edge. Note the unexpected depression in band-gap for all nanoparticle sizes at about 60% Te. The generally successful Vegard's law (4) for thin-film and bulk alloys is linear,

Ealloy = xEA + (1 - x)EB

where x = mole fraction, and EA, EB and Ealloy are the band-gaps for pure materials A, B and alloy of A and B respectively. Vegard's law, however, is only a first approximation, and others (5) have found this "optical bowing" in bulk CdSeTe, so this effect is not solely caused by quantum confinement.

Figure 2. Composition versus absorpotion and emission energies for CdSe1-xTex nanoparticles. (a) Absorption and photoluminescence of CDSe0.34Te0.66 QDs; (b) absorption-energy onset related to Te content; (c) emission peak-wavelength versus Te content.


Zunger et al. (6,7) suggest the observed effects arise because of: (a) the various ionic sizes in the alloy; (b) the various electronegativities of these ions; and (c) the binary structures of these ions have various lattice constants. Relaxation of the ionic bonds to equilibrium positions may lead to local order in the structure and a larger than expected reduction in the band-gap.


Conclusions
Particle size and composition can control quantum confinement. These QDs may be useful for molecular imaging in living systems, because of their near-IR and far-red fluorescence, where deep-tissue imaging is necessary, away from blood and water light-absorption QDs also provide absorption coefficients an order-of-magnitude larger than typical organic dyes. The ultra-sensitive Spex FluoroMax spectrofluorometer is useful in a wide array of research related to nanostructures and materials science for the future.


Acknowledgements
Data and images from Robert Bailey at Oxford University, and Shuming Nie at Emory University and Georgia Institute of Technology are gratefully acknowledged.


Reference
1. R. E. Bailey and S. Nie, Journal of the American Chemical Society 125, 7100-7106 (2003).

2. Y. Tian, T. Newton, N. A. Kotov, D. M. Guldi, and J. H. Fendler, Journal of Physical Chemistry, 100, 8927-8939 (1996).

3. R. K. Richardson and H/ L/ Goering, Eds., Compound Semiconductors (Reinhold, New York, 1962).

4. L. Z. Vegard, Zeitschrift fr Physik 5, 17-26 (1921).

5. H. C. Poon, Z. C. Feng, Y. P. Feng, and M. F. Li, Journal of Physics: Condensed Matter 7, 2783-2799 (1995).

6. J. E. Bernard and A. Zunger, Physical Review B 36, 3199-3326 (1987).

7. S. H. Wei, S. B. Zhang, and A. Zunger, Journal of Applied Physics 87, 1304-1311 (2000).


back to top
'"/>

Source:


Page: All 1 2 3 4

Related biology technology :

1. Improved Quantitative Selectivity of Clenbuterol in Human Urine using High Resolution on the TSQ Quantum Mass Spectrometer
2. Bioanalytical Method Intraday Validation for the Quantitation of Paroxetine in Bovine Plasma using the TSQ Quantum Mass Spectrometer
3. Quantitation of Acrylamide in Food Samples on the Finnigan TSQ Quantum Discovery by LC/APCI-MS/MS
4. Increased Analyte Sensitivity through the Utility of Enhanced Mass-Resolution on the FinniganTSQ Quantum Discovery
5. FluoroMax multiwavelength capability
Post Your Comments:
*Name:
*Comment:
*Email:


(Date:6/27/2016)... ... ... Parallel 6 , the leading software as a service (SaaS) provider ... Patient Encounter CONSULT module which enables both audio and video telemedicine communication between the ... the CONSULT module, patients and physicians can schedule a face to face virtual patient ...
(Date:6/24/2016)... 24, 2016  Regular discussions on a range of subjects ... the two entities said Poloz. Speaking at a ... , he pointed to the country,s inflation target, which ... "In certain areas ... have common economic goals, why not sit down and address ...
(Date:6/23/2016)... ... June 23, 2016 , ... UAS ... the launch of their brand, UP4™ Probiotics, into Target stores nationwide. The company, ... proud to add Target to its list of well-respected retailers. This list includes ...
(Date:6/23/2016)... ... June 23, 2016 , ... ... and Mold) microbial test has received AOAC Research Institute approval 061601. , “This ... introduced last year,” stated Bob Salter, Vice President of Regulatory and Industrial Affairs. ...
Breaking Biology Technology:
(Date:4/13/2016)... April 13, 2016  IMPOWER physicians supporting Medicaid patients ... a new clinical standard in telehealth thanks to a ... the higi platform, IMPOWER patients can routinely track key ... body mass index, and, when they opt in, share ... visit to a local retail location at no cost. ...
(Date:3/31/2016)... 2016  Genomics firm Nabsys has completed a financial ... Bready , M.D., who returned to the company in ... leadership team, including Chief Technology Officer, John Oliver ... Nurnberg and Vice President of Software and Informatics, ... Dr. Bready served as CEO of Nabsys from ...
(Date:3/23/2016)... 2016 Einzigartige ... und Stimmerkennung mit Passwörtern     ... MESG ), ein führender Anbieter digitaler Kommunikationsdienste, ... SpeechPro zusammenarbeitet, um erstmals dessen Biometrietechnologie einzusetzen. ... Möglichkeit angeboten, im Rahmen mobiler Apps neben ...
Breaking Biology News(10 mins):