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Tin nanocrystals for the battery of the future
Date:4/8/2013

This press release is available in German.

They provide power for electric cars, electric bicycles, Smartphones and laptops: nowadays, rechargeable lithium ion batteries are the storage media of choice when it comes to supplying a large amount of energy in a small space and lightweight. All over the world, scientists are currently researching a new generation of such batteries with an improved performance. Scientists headed by Maksym Kovalenko from the Laboratory of Inorganic Chemistry at ETH Zurich and Empa have now developed a nanomaterial which enables considerably more power to be stored in lithium ion batteries.

The nanomaterial is composed of tiny tin crystals, which are to be deployed at the minus pole of the batteries (anode). When charging the batteries, lithium ions are absorbed at this electrode; while discharging, they are released again (see box). "The more lithium ions the electrodes can absorb and release the better they can breathe, as it were the more energy can be stored in a battery," explains Kovalenko.

Uniform crystals

The element tin is ideal for this: every tin atom can absorb at least four lithium ions. However, the challenge is to deal with the volume change of tin electrodes: tin crystal becomes up to three times bigger if it absorbs a lot of lithium ions and shrinks again when it releases them back. The scientists thus resorted to nanotechnology: they produced the tiniest tin nanocrystals and embedded a large number of them in a porous, conductive permeable carbon matrix. Much like how a sponge can suck up water and release it again, an electrode constructed in this way can absorb lithium ions while charging and release them when discharging. If the electrode were made of a compact tin block, this would practically be impossible.

During the development of the nanomaterial, the issue of the i
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Contact: Maksym Kovalenko
mvkovalenko@ethz.ch
41-446-334-156
ETH Zurich
Source:Eurekalert

Page: 1 2 3

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