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Small ... smaller ... smallest? ASU researchers create molecular diode
Date:10/13/2009

Recently, at Arizona State University's Biodesign Institute, N.J. Tao and collaborators have found a way to make a key electrical component on a phenomenally tiny scale. Their single-molecule diode is described in this week's online edition of Nature Chemistry.

In the electronics world, diodes are a versatile and ubiquitous component. Appearing in many shapes and sizes, they are used in an endless array of devices and are essential ingredients for the semiconductor industry. Making components including diodes smaller, cheaper, faster and more efficient has been the holy grail of an exploding electronics field, now probing the nanoscale realm.

Smaller size means cheaper cost and better performance for electronic devices. The first generation computer CPU used a few thousand transistors, Tao says noting the steep advance of silicon technology. "Now even simple, cheap computers use millions of transistors on a single chip."

But lately, the task of miniaturization has gotten much harder, and the famous dictum known as Moore's lawwhich states that the number of silicon-based transistors on a chip doubles every 18-24 monthswill eventually reach its physical limits. "Transistor size is reaching a few tens of nanometers, only about 20 times larger than a molecule," Tao says. "That's one of the reasons people are excited about this idea of molecular electronics."

Diodes are critical components for a broad array of applications, from power conversion equipment, to radios, logic gates, photodetectors and light-emitting devices. In each case, diodes are components that allow current to flow in one direction around an electrical circuit but not the other. For a molecule to perform this feat, Tao explains, it must be physically asymmetric, with one end capable of forming a covalent bond with the negatively charged anode and the other with the positive cathode terminal.

The new study compares a symmetric molecule wit
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Contact: Joe Caspermeyer
joseph.caspermeyer@asu.edu
480-727-0369
Arizona State University
Source:Eurekalert  

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