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Graphene oxide, a single-atomic-layered material made by reacting graphite powders with strong oxidizing agents, has attracted a lot of interest from scientists because of its ability to easily convert to graphene a hotly studied material that scientists believe could be used to produce low-cost carbon-based transparent and flexible electronics.
But to Jiaxing Huang, assistant professor of materials science and engineering, and his research group at the McCormick School of Engineering and Applied Science at Northwestern University, graphene oxide itself is even more interesting. Huang and his group have studied the material for years and have discovered how to assemble these soft sheets like floating water lilies pads. They also used a camera flash to turn them into graphene, and invented a fluorescence quenching technique to make them visible under microscopes.
Now, working with Kenneth R. Shull, professor of materials science and engineering, they have discovered that graphene oxide sheets behave like surfactants, the chemicals in soap and shampoo that make stains disperse in water. The team's results are published online in the Journal of the American Chemical Society.
Graphene oxide has been known in the scientific world for more than a century and was largely described as hydrophilic, or attracted to water. But Huang and his research group thought that graphene oxide should be amphiphilic, a property of surfactants that can both attracts and repels water, because part of the graphene oxide structure is actually water repelling.
"We view graphene oxide as a soft material," Huang says. "For example, it is essentially two-dimensional polymers composed of carbon, hydrogen and oxygen. They are also colloidal particles with very exotic shapes."
To test their hypothesis, Huang and his group put graphene oxide in carbonated water. They found that the sheets can hitchhike onto the rising bubbles to reach the wate
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| Contact: Megan Fellman fellman@northwestern.edu 847-491-3115 Northwestern University Source:Eurekalert |