PHILADELPHIA - Material scientists at the Nano/Bio Interface Center of the University of Pennsylvania have demonstrated the transduction of optical radiation to electrical current in a molecular circuit. The system, an array of nano-sized molecules of gold, respond to electromagnetic waves by creating surface plasmons that induce and project electrical current across molecules, similar to that of photovoltaic solar cells.
The results may provide a technological approach for higher efficiency energy harvesting with a nano-sized circuit that can power itself, potentially through sunlight. Recently, surface plasmons have been engineered into a variety of light-activated devices such as biosensors.
It is also possible that the system could be used for computer data storage. While the traditional computer processor represents data in binary form, either on or off, a computer that used such photovoltaic circuits could store data corresponding to wavelengths of light.
Because molecular compounds exhibit a wide range of optical and electrical properties, the strategies for fabrication, testing and analysis elucidated in this study can form the basis of a new set of devices in which plasmon-controlled electrical properties of single molecules could be designed with wide implications to plasmonic circuits and optoelectronic and energy-harvesting devices.
Dawn Bonnell, a professor of materials science and the director of the Nano/Bio Interface Center at Penn, and colleagues fabricated an array of light sensitive, gold nanoparticles, linking them on a glass substrate. Minimizing the space between the nanoparticles to an optimal distance, researchers used optical radiation to excite conductive electrons, called plasmons, to ride the surface of the gold nanoparticles and focus light to the junction where the molecules are connected. The plasmon effect increases the efficiency of current production in the molecule by a factor of 400 to
|Contact: Jordan Reese|
University of Pennsylvania