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Nanoparticle electrode for batteries could make grid-scale power storage feasible
Date:11/23/2011

The sun doesn't always shine and the breeze doesn't always blow and therein lie perhaps the biggest hurdles to making wind and solar power usable on a grand scale. If only there were an efficient, durable, high-power, rechargeable battery we could use to store large quantities of excess power generated on windy or sunny days until we needed it. And as long as we're fantasizing, let's imagine the battery is cheap to build, too.

Now Stanford researchers have developed part of that dream battery, a new electrode that employs crystalline nanoparticles of a copper compound.

In laboratory tests, the electrode survived 40,000 cycles of charging and discharging, after which it could still be charged to more than 80 percent of its original charge capacity. For comparison, the average lithium ion battery can handle about 400 charge/discharge cycles before it deteriorates too much to be of practical use.

"At a rate of several cycles per day, this electrode would have a good 30 years of useful life on the electrical grid," said Colin Wessells, a graduate student in materials science and engineering who is the lead author of a paper describing the research, published this week in Nature Communications.

"That is a breakthrough performance a battery that will keep running for tens of thousands of cycles and never fail," said Yi Cui, an associate professor of materials science and engineering, who is Wessell's adviser and a coauthor of the paper.

The electrode's durability derives from the atomic structure of the crystalline copper hexacyanoferrate used to make it. The crystals have an open framework that allows ions electrically charged particles whose movements en masse either charge or discharge a battery to easily go in and out without damaging the electrode. Most batteries fail because of accumulated damage to an electrode's crystal structure.

Because the ions can move so freely, the electrode's cycle of
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Contact: Louis Bergeron
louisb3@stanford.edu
650-725-1944
Stanford University
Source:Eurekalert

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