Navigation Links
Layered graphene sheets could solve hydrogen storage issues
Date:3/17/2010

Graphenecarbon formed into sheets a single atom thicknow appears to be a promising base material for capturing hydrogen, according to recent research* at the National Institute of Standards and Technology (NIST) and the University of Pennsylvania. The findings suggest stacks of graphene layers could potentially store hydrogen safely for use in fuel cells and other applications.

Graphene has become something of a celebrity material in recent years due to its conductive, thermal and optical properties, which could make it useful in a range of sensors and semiconductor devices. The material does not store hydrogen well in its original form, according to a team of scientists studying it at the NIST Center for Neutron Research. But if oxidized graphene sheets are stacked atop one another like the decks of a multilevel parking lot, connected by molecules that both link the layers to one another and maintain space between them, the resulting graphene-oxide framework (GOF) can accumulate hydrogen in greater quantities.

Inspired to create GOFs by the metal-organic frameworks that are also under scrutiny for hydrogen storage, the team is just beginning to uncover the new structures' properties. "No one else has ever made GOFs, to the best of our knowledge," says NIST theorist Taner Yildirim. "What we have found so far, though, indicates GOFs can hold at least a hundred times more hydrogen molecules than ordinary graphene oxide does. The easy synthesis, low cost and non-toxicity of graphene make this material a promising candidate for gas storage applications."

The GOFs can retain 1 percent of their weight in hydrogen at a temperature of 77 degrees Kelvin and ordinary atmospheric pressureroughly comparable to the 1.2 percent that some well-studied metal-organic frameworks can hold, Yildirim says.

Another of the team's potentially useful discoveries is the unusual relationship that GOFs exhibit between temperature and hydrogen absorption. In most storage materials, the lower the temperature, the more hydrogen uptake normally occurs. However, the team discovered that GOFs behave quite differently. Although a GOF can absorb hydrogen, it does not take in significant amounts at below 50 Kelvin (-223 degrees Celsius). Moreover, it does not release any hydrogen below this "blocking temperature"suggesting that, with further research, GOFs might be used both to store hydrogen and to release it when it is needed, a fundamental requirement in fuel cell applications.

Some of the GOFs' capabilities are due to the linking molecules themselves. The molecules the team used are all benzene-boronic acids that interact strongly with hydrogen in their own right. But by keeping several angstroms of space between the graphene layersakin to the way pillars hold up a ceilingthey also increase the available surface area of each layer, giving it more spots for the hydrogen to latch on.

According to the team, GOFs will likely perform even better once the team explores their parameters in more detail. "We are going to try to optimize the performance of the GOFs and explore other linking molecules as well," says Jacob Burress, also of NIST. "We want to explore the unusual temperature dependence of absorption kinetics, as well as whether they might be useful for capturing greenhouse gases such as carbon dioxide and toxins like ammonia."


'/>"/>

Contact: Chad Boutin
boutin@nist.gov
301-975-4261
National Institute of Standards and Technology (NIST)
Source:Eurekalert  

Related biology technology :

1. New graphene nanomesh could change the future of electronics
2. Study quantifies the electron transport effects of placing metal contacts onto graphene
3. Single-step technique produces both p-type and n-type doping for future graphene devices
4. UC Riverside graphene specialist Jeanie Lau receives national honor at White House
5. New study confirms exotic electric properties of graphene
6. Researchers design new graphene-based, nanomaterial with magnetic properties
7. Researchers design new graphene-based, nano-material with magnetic properties
8. UCR scientists manipulate ripples in graphene, enabling strain-based graphene electronics
9. Material world: Graphenes versatility promises new applications
10. Bilayer graphene gets a bandgap
11. Graphene may have advantages over copper for IC interconnects at the nanoscale
Post Your Comments:
*Name:
*Comment:
*Email:
Related Image:
Layered graphene sheets could solve hydrogen storage issues
(Date:6/23/2016)... ... June 23, 2016 , ... Supplyframe, the ... the Supplyframe Design Lab . Located in Pasadena, Calif., the Design Lab’s ... how hardware projects are designed, built and brought to market. , The Design ...
(Date:6/23/2016)... ... , ... In a new case report published today in STEM CELLS Translational ... lymphedema after being treated for breast cancer benefitted from an injection of stem cells ... this debilitating, frequent side effect of cancer treatment. , Lymphedema refers to ...
(Date:6/23/2016)... 23, 2016  Blueprint Bio, a company dedicated to ... medical community, has closed its Series A funding round, ... "We have received a commitment from Forentis ... need to meet our current goals," stated Matthew ... runway to complete validation on the current projects in ...
(Date:6/23/2016)... 23, 2016 On Wednesday, June 22, ... down 0.22%; the Dow Jones Industrial Average edged 0.27% lower ... 2,085.45, down 0.17%. Stock-Callers.com has initiated coverage on the following ... Therapeutics (NASDAQ: NKTR ), Aralez Pharmaceuticals Inc. (NASDAQ: ... BIND ). Learn more about these stocks by accessing ...
Breaking Biology Technology:
(Date:5/12/2016)... DALLAS , May 12, 2016 ... has just published the overview results from the Q1 ... of the recent wave was consumers, receptivity to a ... wearables data with a health insurance company. ... choose to share," says Michael LaColla , CEO ...
(Date:5/3/2016)... 2016  Neurotechnology, a provider of high-precision biometric ... Biometric Identification System (ABIS) , a complete system ... ABIS can process multiple complex biometric transactions with ... fingerprint, face or iris biometrics. It leverages the ... MegaMatcher Accelerator , which have been used ...
(Date:4/28/2016)... First quarter 2016:   , ... the first quarter of 2015 The gross margin was ... 18.8) and the operating margin was 40% (-13) Earnings ... flow from operations was SEK 249.9 M (21.2) , ... SEK 7,000-8,500 M. The operating margin for 2016 is ...
Breaking Biology News(10 mins):