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Heavy metals open path to high temperature nanomagnets
Date:3/28/2011

How would you like to store all the films ever made on a device the size of an I-phone?

Magnets made of just a few metallic atoms could make it possible to build radically smaller storage devices and have also recently been proposed as components for spintronics devices. There's just one obstacle on the way. Nano-sized magnets have only been seen to work at temperatures a few hairs above absolute zero.

Now a chemistry student at the University of Copenhagen has demonstrated that molecular magnets using the metals ruthenium and osmium retain their magnetic properties at higher temperatures. Most likely due to the larger spin-orbit coupling and more diffuse electron cloud present in these heavier elements. Some of his findings have recently been published in Chemistry A European Journal.

Kasper Steen Pedersen is studying for a Masters degree at the University of Copenhagen. Like many others in his chosen field of molecular magnetism he had been working with magnets based on 3d metal ions from iron. This seems an obvious choice when working with ordinary magnets which usually consist of about a trillion atoms. Single-molecule magnets are isolated molecules behaving like real magnets but they do not exhibit a three-dimensional order characteristic of a magnet. Though interesting from a perspective of fundamental research, the need for very low temperatures make the miniscule magnets useless for any practical applications. So Pedersen wanted to see if another tack was possible.

"When you take a look at the periodic table of the elements the solution seems obvious. Ruthenium and osmium are in the same group in the periodic table as iron, so it ought to be possible to create magnets out of these substances as well by using our knowledge about molecular magnets based on iron" says Pedersen.

As it turned out the chemical synthesis needed to build molecular magnets out of the substances was relatively simple. But the measured properti
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Contact: Jes Andersen
jean@science.ku.dk
45-2360-1140
University of Copenhagen
Source:Eurekalert  

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