Navigation Links
Golden nanocrown
Date:5/14/2008

This release is available in German.

Chinese researchers have recently made a golden crown with a diameter of only a few nanometers. It is a large ring-shaped molecule containing 36 gold atoms. The lords of the ring, a team of researchers from the Universities of Beijing, Hong Kong, and Nanjing report their unusual compound in the journal Angewandte Chemie: the molecular ring structure is held together exclusively by goldgold bonds and is thus the largest ring system made of gold atoms produced to date.

Large molecular rings have fascinated chemists for over 40 yearsever since the discovery of crown ethers in 1967. The pioneers in this area, C. J. Pederson, J.-M. Lehn, and D. J. Cram received the Nobel Prize in Chemistry for their discovery in 1987. In the meantime, large molecular ring systems have played an important role in the search for new functional materials and in nanotechnology. The synthesis of ring systems held together exclusively by metalmetal bonds has remained a challenge.

Small rings made of positively charged gold atoms have been know for some time, but only recently could the Chinese team make a ring containing 16 gold atoms. Now, the researchers, led by Shu-Yan Yu, Yi-Zhi Li, and Vivian Wing-Wah Yam, have introduced a new representative of this class of compounds, the biggest gold ring to date that is held together by means of goldgold bonds: a ring system containing 36 univalent gold atoms.

The researchers started their synthesis with a ring system containing six gold atoms. Three of the gold atoms are linked into a triangle. Each of these gold atoms is attached to another gold atom that sticks out from the corner of the triangle. Three organic ligands are then bound to this flat double triangle to form a molecule that resembles a three-blade propeller.

Six such propellers can be linked into a larger ring by means of a self-assembly process. Within this ring system, the gold atoms are arranged into a shape that resembles a crown: six double triangles are each bound to each other by two corners. The free double-corners point outward in a pattern that alternates above and below the plane of the ring.


'/>"/>

Contact: Shu-Yan Yu
yusy@chem.ruc.edu.cn
Wiley-Blackwell
Source:Eurekalert  

Related biology technology :

1. Emmy(R)- and Golden Globe(R)-Nominated Actress Marcia Cross to Join Lifetime Networks and Members of Congress From Both Parties at Capitol Hill Press Conference
Post Your Comments:
*Name:
*Comment:
*Email:
Related Image:
Golden nanocrown
(Date:1/18/2017)... ... 2017 , ... Announced in December 2016, RoosterBio is now ... of Commerce Penny Pritzker has announced the award of a new National Institute ... the award of a new Advanced Regenerative Manufacturing Institute (ARMI). These are the ...
(Date:1/18/2017)... ... 18, 2017 , ... Researchers from a new study are stating that if levels ... prostate cancer treatment, this indicates there is still remaining prostate cancer cells that are more ... PSA test has always been an indicator of whether a man’s prostate cancer is ...
(Date:1/18/2017)... ... 18, 2017 , ... BidMed, LLC, announced it will hold a ... lab equipment from two different leading institutes. This highly specialized laboratory equipment is coming ... States. This 1-day online auction will take place on BidMed’s website http://www.bidmed.com ...
(Date:1/18/2017)... ... January 18, 2017 , ... Thirty-six startup companies in ... by the Pennsylvania Department of Community and Economic Development in 2016 as part of ... in the University City Keystone Innovation Zone and represent the highest number of awards ...
Breaking Biology Technology:
(Date:1/6/2017)... JOLLA, Calif. , Jan. 6, 2017 /PRNewswire/ ... 1 safety studies in healthy volunteers of a ... intended to treat acute pancreatitis. ... is typically a mild disorder, but can be ... organ failure and sepsis, where extended hospital stays, ...
(Date:1/4/2017)... , Jan. 4, 2017  CES 2017 – ... sensor technology, today announced the launch of two ... systems, the highly-accurate biometric sensor modules that incorporate ... technology, experience and expertise. The two new designs ... specifically for hearables, and Benchmark BW2.0, a 2-LED ...
(Date:12/20/2016)... 20, 2016 The rising popularity of ... leasing is stoking significant interest in keyless access ... Bluetooth low energy (BLE), biometrics and near-field communication ... wave of wireless technologies in the automotive industry. ... advanced access systems opens the market to specialist ...
Breaking Biology News(10 mins):