A new study by a team including scientists from the National Institute of Standards and Technology (NIST) indicates that thin polymer films can have different properties depending on the method by which they are made. The results* suggest that deeper work is necessary to explore the best way of creating these films, which are used in applications ranging from high-tech mirrors to computer memory devices.
Thin films spread atop a surface have many applications in industry. Inexpensive organic solar cells might be made of such films, to name one potential use. Typically they're made by dissolving the polymer, and then spreading a small amount of the liquid out on a surface, called a substrate. The solution becomes a film as the solvent dries and the remainder solidifies. But as this happens, stresses develop within the film that can affect its structure.
Manufacturers would like to know more about how to control these stresses to ensure the film does what they want. But scientists who study film formation often use a different method of casting films than a manufacturer would. One method used in industry is "flow coating"similar to spreading frosting across a cake. Another method is "spin casting"placing a drop of liquid on a substrate that spins rapidly and spreads the droplet out evenly by centrifugal force. Both methods create smooth films generally, but the team decided to examine whether the two methods create different effects in finished films consisting of a self-assembling block copolymer.
"It's an important question because some proposed applications intend to take advantage of these effects," Douglas says.
The team's comparison led to results that surprised them. Although the rapid spinning of spin casting is very dynamic, suggesting it would convey more stress to the resulting film, it actually led to fewer residual stresses than flow coating did. As previous studies have shown that leftover solvent can lead to
|Contact: Chad Boutin|
National Institute of Standards and Technology (NIST)