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Berkeley researchers take the lead out of piezoelectrics
Date:11/13/2009

e should be generic to other lead-free perovskites as well," Ramesh says, "akin to chemically driven effects that are now well established in the manganites, cuprates and relaxors."

Piezoelectric materials, as a result of their unique crystal structures, are able to couple mechanical and electrical properties. Place a mechanical strain on a piezoelectric and an electric charge is generated across its surface. Subject a piezoelectric to an electric charge and its shape becomes deformed. The electromechanical properties of piezoelectric materials have made them valuable components in a broad range of devices, including sensors, actuators and transducers. They are especially valuable for medical ultrasounds and for non-destructive testing of roads and bridges.

The most widely used piezoelectric materials today are lead-based perovskite compounds, especially lead zirconate titanate (PZT). These perovskites display superior piezoelectric properties in areas where the phase of their crystal structure abruptly changes. Such areas, known as morphotropic phase boundaries, are produced via complex chemical alloying of a PZT-type perovskite's metal and oxide constituents. While the technology is well established, lead is a potent neurotoxin that poses a serious threat to human health, especially children, and to the environment.

"We have produced the piezoelectric effect by taking thin films of bismuth ferrite and applying a huge epitaxial strain," says Robert Zeche, a member of Ramesh's UC Berkeley research group who was the first author on the Science paper. "The bismuth ferrite wants to be in a rhombohedral phase but the epitaxial strain forces it into a tetragonal phase, creating a morphotropic phase boundary."

If the strain is removed, the bismuth ferrite crystal structure reverts back to its original rhombohedral-like phase, Zeche says. By alternating between squeezing and relaxing, the researchers can shuttle the material bac
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Contact: Lynn Yarris
lcyarris@lbl.gov
510-486-5375
DOE/Lawrence Berkeley National Laboratory
Source:Eurekalert  

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