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A shock to pollution in chemistry
Date:12/4/2012

eactants and catalysts in a rapidly vibrating jar. Chemical transformations take place at the sites of ball collision, where impact causes instant "hot spots" of localized heat and pressure. This is difficult to model and, without access to real time reaction monitoring, mechanochemistry remained poorly understood. "When we set out to study these reactions, the challenge was to observe the entire reaction without disturbing it, in particular the short-lived intermediates that appear and disappear under continuous impact in less than a minute", says Tomislav Fričić, a Professor at McGill University in Montreal.

The team of scientists chose to study mechanochemical production of the metal-organic framework ZIF-8 (sold as Basolite Z1200) from the simplest and non-toxic components. Materials such as ZIF-8 are rapidly gaining popularity for capturing large amounts of CO2 and, if manufactured cheaply and sustainably, could become widely used for carbon capture, catalysis and even hydrogen storage. "The team came to the ESRF because of our high-energy X-rays capable of penetrating 3 mm thick walls of a rapidly moving reaction jar made of steel, aluminium or plastic. The X-ray beam must get inside the jar to probe the mechanochemical formation of ZIF-8, and then out again to detect the changes as they happened", says Simon Kimber, a scientist at the European Synchrotron Radiation Facility (ESRF) in Grenoble, who is a member of the team. This unprecedented methodology enabled the real-time observation of reaction kinetics, reaction intermediates and the development of their respective nanoparticles.

This technique is not limited to ZIF-8. In principle, all types of chemical reactions in a ball mill can now be studied and optimized for industrial processing. 'These results hold promise for improving the fundamental understanding of processes central to pharmaceutical, metallurgical, cement and mineral industries and should enable a more
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Contact: Claus habfast
claus.habfast@esrf.fr
33-666-662-384
European Synchrotron Radiation Facility
Source:Eurekalert  

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