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MIT engineers probe spiders' polymer art

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"This is pretty scary," he said. "I'd never seen a spider this big. I never grew up around anything with furry knuckles." But he quickly settled into dissecting the peanut-sized and -shaped protuberance on the spiders' backs containing their silk-producing glands and spinnerets.

Spiders don't actually spin ("spinning" refers to the age-old art of drawing out and twisting fibers to form thread); instead, they squirt out a thick gel of silk solution. (One teaspoonful can make 10,000 webs.) They then use their hind legs as well as their body weight and gravity to elongate the gel into a fine thread.

Kojic, who first practiced on silkworms, learned how to extract a microscopic amount of the gel-like solution from the spider's silk-producing major ampullate gland.

The researchers used devices called micro-rheometers-custom-made to handle the tiny drops of silk solution-to test the material's behavior when subjected to forces. The team tested the thick solution's viscosity, or how it flowed, by "shearing" it, or placing it between two rapidly moving glass plates. They tested its stickiness by pulling it apart, like taffy, between two metal plates.

The magic that makes silk so strong, the researchers discovered, happens while it flows out of the spider's gland, lengthens into a filament and dries.

Engineering Nature

The key to spider silk is polymers.

Plastics, Kevlar (used in bulletproof vests) and parts of the International Space Station are some of the many items made from polymers. The proteins in our bodies are polymers made from amino acids. From the Greek for "many" and "units," polymers are long linked chains of small molecules. They can be flexible or stiff, water-soluble or insoluble, resistant to heat and chemicals and very strong.

Silk protein solution consists of 30-40 percent polymers; the rest is water. The spider's silk-producing glands are capable of synthesizing large f
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Source:Massachusetts Institute of Technology


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