Navigation Links
UNC study on properties of carbon nanotubes, water could have wide-ranging implications
Date:10/2/2008

CHAPEL HILL A fresh discovery about the way water behaves inside carbon nanotubes could have implications in fields ranging from the function of ultra-tiny high-tech devices to scientists' understanding of biological processes, according to researchers from the University of North Carolina at Chapel Hill.

The findings, published in the Oct. 3, 2008, issue of the journal Science, relate to a property of so-called "nano-confined" water specifically, whether hollow carbon nanotubes take in the liquid easily or reluctantly, depending on their temperature.

As well as shedding light on the characteristics of human-made nanomaterials, researchers note that such properties are relevant to the workings of biological structures and phenomena which also function at nano-scales.

The team of scientists, led by Yue Wu, Ph.D., professor of physics in the UNC College of Arts and Sciences, examined carbon nanotubes measuring just 1.4 nanometers in diameter (one nanometer is a billionth of a meter). The seamless cylinders were made from rolled up graphene sheets, the exfoliated layer of graphite.

"Normally, graphene is hydrophobic, or 'water hating' it repels water in the same way that drops of dew will roll off a lotus leaf," said Wu. "But we found that in the extremely limited space inside these tubes, the structure of water changes, and that it's possible to change the relationship between the graphene and the liquid to hydrophilic or 'water-liking'."

The UNC team did this by making the tubes colder. Using nuclear magnetic resonance similar to the technology used in advanced medical MRI scanners they found that at about room temperature (22 degrees centigrade), the interiors of carbon nanotubes take in water only reluctantly.

However, when the tubes were cooled to 8 degrees, water easily went inside. Wu said this shows that it is possible for water in nano-confined regions either human-made or natural to take on different structures and properties depending on the size of the confined region and the temperature.

In terms of potential practical applications, Wu suggested further research along these lines could impact the design of high-tech devices (for example, nano-fluidic chips that act as microscopic laboratories), microporous sorbent materials such as activated carbon used in water filters, gas masks, and permeable membranes.

"It may be that by exploiting this hydrophobic-hydrophilic transition, it might be possible to use changes in temperature as a kind of 'on-off' switch, changing the stickiness of water through nano-channels, and controlling fluid flow."

Wu also noted that this research relates to scientists' understanding of the workings of many building blocks of life (such as proteins, whose structures also have nano-confined hydrophobic regions) and how their interaction with water plays a role in how they function. For example, such interactions play an important role in the process known as "protein folding," which determines a protein's eventual shape and characteristics. Misfolded proteins are believed to be a cause of several neurodegenerative and other diseases.

"We don't fully understand the mechanisms behind protein unfolding upon cooling," Wu said. "Could this kind of cooling-induced hydrophobic-hydrophilic transition play a role? We don't know but it's worth investigating."


'/>"/>

Contact: Patric Lane
patric_lane@unc.edu
919-962-8596
University of North Carolina at Chapel Hill
Source:Eurekalert

Related biology news :

1. Childhood obesity indicates greater risk of school absenteeism, Penn study reveals
2. A study by the MUHC and McGill University opens a new door to understanding cancer
3. Study begins to reveal clues to the cause and progression of sepsis
4. Clones on task serve greater good, evolutionary study shows
5. New study warns limited carbon market puts 20 percent of tropical forest at risk
6. New study examines how rearing environment can alter navigation
7. Study links cat disease to flame retardants in furniture and to pet food
8. New continent and species discovered in Atlantic study
9. Study shows link between alcohol consumption and hiv disease progression
10. Feeling hot, hot, hot: New study suggests ways to control fever-induced seizures
11. Study finds environmental tests help predict hospital-acquired Legionnaires disease risk
Post Your Comments:
*Name:
*Comment:
*Email:
(Date:11/22/2016)... November 22, 2016 According to the new market ... Print, Face, Vein, Signature, Voice), Multi-Factor), Component (Hardware and Software), Function (Contact ... MarketsandMarkets, the market is expected to grow from USD 10.74 Billion in ... 16.79% between 2016 and 2022. Continue Reading ... ...
(Date:11/21/2016)... , Nov. 21, 2016   Neurotechnology ... object recognition technologies, today announced that the MegaMatcher ... cards was submitted for the NIST Minutiae ... passed all the mandatory steps of the evaluation ... is a continuing test of fingerprint templates used ...
(Date:11/17/2016)... -- Global Market Watch: Primarily supported by ownership ... and Academics) market is to witness a value of US$37.1 ... highest Compounded Annual Growth Rate (CAGR) of 10.75% is foreseen ... period 2014-2020. North America is not ... Europe at 9.56% respectively. Report Focus: ...
Breaking Biology News(10 mins):
(Date:12/2/2016)... ... December 02, 2016 , ... Robots will storm the Prudential Center in ... 2016. The event, which is held on the United Nations International Day of Persons ... back into the workplace. Suitable Technologies is partnering with NTI to showcase how technology ...
(Date:11/30/2016)... , ... November 30, 2016 , ... ... moving magnet Voice Coil Actuator with a flexure design that ensures high alignment ... with cost-effective pricing and is ideally suited where extreme precision is required, such ...
(Date:11/30/2016)... 30, 2016 Biotest Pharmaceuticals Corporation (BPC), a ... announce the addition of its newest plasma collection center ... . The 15,200 square foot state-of-the-art facility officially ... and brings the total number of BPC,s plasma collection ... , BPC,s Chief Executive Officer said "We are pleased ...
(Date:11/30/2016)... DIEGO and BEIJING , ... a leading commercial provider of genomic services and solutions ... announced today that it has completed a USD $75 ... Merchants Bank Co., Ltd.,s CMB International Capital Management ( ... Innovation Investment Management Co., Ltd. ("SDIC Innovation") and Shanghai ...
Breaking Biology Technology: