Navigation Links
The search for improved carbon sponges picks up speed
Date:5/27/2010

Jeffrey Long's lab will soon host a round-the-clock, robotically choreographed hunt for carbon-hungry materials.

The Lawrence Berkeley National Laboratory chemist leads a diverse team of scientists whose goal is to quickly discover materials that can efficiently strip carbon dioxide from a power plant's exhaust, before it leaves the smokestack and contributes to climate change.

They're betting on a recently discovered class of materials called metal-organic frameworks that boast a record-shattering internal surface area. A sugar cube-sized piece, if unfolded and flattened, would more than blanket a football field. The crystalline material can also be tweaked to absorb specific molecules.

The idea is to engineer this incredibly porous compound into a voracious sponge that gobbles up carbon dioxide.

And they're going for speed. The scientists hope to discover this dream material in a breakneck three years, maybe sooner. To do this, they'll create an automated system that simultaneously synthesizes hundreds of metal-organic frameworks, then screens the most promising candidates for further refinement.

"Our discovery process will be up to 100 times faster than current techniques," says Long. "We need to quickly find next-generation materials that capture and release carbon without requiring a lot of energy."

Carbon capture is the first step in carbon capture and storage, a climate change mitigation strategy that involves pumping compressed carbon dioxide captured from large stationary sources into underground rock formations that can store it for geological time scales. Many scientists believe the technology is key to curbing the amount of carbon dioxide that enters the atmosphere. Fossil fuels such as coal and natural gas will likely remain cheap and plentiful energy sources for decades to come even with the continued development of renewable energy sources.

Carbon capture and storage is being tested on a large scale in only a few places worldwide. One of the biggest obstacles to industrial-scale implementation is its parasitic energy cost. Today's carbon capture materials, such as liquid amine scrubbers, sap a whopping 30 percent of the power generated by a power plant.

To overcome this, scientists are seeking alternatives that can be used again and again with minimal energy costs. It's a slow, finicky process. Promising materials such as metal-organic frameworks come in millions of variations, only a handful of which are conducive to capturing carbon. Finding just the right material may take years.

That could change. In early May, Long's team began negotiating a three-year, $3.6 million grant from the Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E) to supercharge the search.

"We want to run the discovery process very rapidly and find materials that only consume 10 percent of a power plant's energy," says Long, who's working with fellow Berkeley Lab scientists Maciej Haranczyk, Eric Masanet, Jeffrey Reimer, and Berend Smit on the project. Together, they'll create a state-of-the-art production line.

A robot will automatically synthesize hundreds of metal-organic frameworks and X-ray diffraction will offer a first-pass evaluation in the search for pure new materials. Magnetic resonance spectroscopy will then ferret out the materials with the pore size distribution best suited for carbon capture.

Next comes the big test: can it capture carbon dioxide from a flue gas? High-throughout gas sorption analysis conducted using new instrumentation built by Wildcat Discovery Technologies of San Diego, California will provide the answer.

Computer algorithms will constantly churn through the resulting data and help refine the next round of synthesis. Promising materials will also be assessed to determine if any ingredients are too expensive for large-scale commercialization.

"We don't want to discover a great material and find it's so expensive that no one will use it," says Long.

As a final test, the Electric Power Research Institute will predict the utility of the best new materials in an industrial-scale carbon capture process.

"We need to find the optimum range of metal-organic frameworks for each power plant," says Long. "Ultimately, this research is intended to lead to materials worthy of large-scale testing and commercialization."


'/>"/>

Contact: Dan Krotz
dakrotz@lbl.gov
510-486-4019
DOE/Lawrence Berkeley National Laboratory
Source:Eurekalert

Related biology news :

1. Research shows skeleton to be endocrine organ
2. Newly created cancer stem cells could aid breast cancer research
3. Dominant cholesterol-metabolism ideas challenged by new research
4. Researchers identify proteins involved in new neurodegenerative syndrome
5. Texas researchers and educators head for Antarctica
6. MGH researchers describe new way to identify, evolve novel enzymes
7. University of Pennsylvania researchers develop formula to gauge risk of disease clusters
8. University of Oregon researcher finds that on waters surface, nitric acid is not so tough
9. U of MN researchers discover noninvasive diagnostic tool for brain diseases
10. U of Minnesota researchers discover noninvasive diagnostic tool for brain diseases
11. Story ideas from the Journal of Lipid Research
Post Your Comments:
*Name:
*Comment:
*Email:
(Date:6/15/2016)... June 15, 2016 Transparency ... titled "Gesture Recognition Market by Application Market - Global Industry Analysis ... 2024". According to the report, the  global gesture recognition ... 2015 and is estimated to grow at a ... by 2024.  Increasing application of gesture ...
(Date:6/2/2016)... , June 2, 2016 The Department ... has awarded the 44 million US Dollar project, for the ... Vehicle Plates including Personalization, Enrolment, and IT Infrastructure , ... in the production and implementation of Identity Management Solutions. Numerous ... however Decatur was selected for the ...
(Date:5/20/2016)... -- VoiceIt is excited to announce its new marketing ... working together, VoiceIt and VoicePass will offer an ... slightly different approaches to voice biometrics, collaboration between ... Both companies ... "This marketing and technology partnership allows VoiceIt ...
Breaking Biology News(10 mins):
(Date:6/24/2016)... ... June 24, 2016 , ... While the majority of ... the Cary 5000 and the 6000i models are higher end machines that use the ... of the spectrophotometer’s light beam from the bottom of the cuvette holder. , ...
(Date:6/23/2016)... ... June 23, 2016 , ... Mosio, a leader ... “Clinical Trials Patient Recruitment and Retention Tips.” Partnering with experienced clinical research professionals, ... providing practical tips, tools, and strategies for clinical researchers. , “The landscape of ...
(Date:6/23/2016)... , June 23, 2016   Boston Biomedical ... novel compounds designed to target cancer stemness pathways, ... been granted Orphan Drug Designation from the U.S. ... of gastric cancer, including gastroesophageal junction (GEJ) cancer. ... designed to inhibit cancer stemness pathways by targeting ...
(Date:6/23/2016)... , June 23, 2016 A person commits a ... crime scene to track the criminal down. An ... Food and Drug Administration (FDA) uses DNA evidence to track ... Sound far-fetched? It,s not. The FDA has increasingly ... support investigations of foodborne illnesses. Put as simply as possible, ...
Breaking Biology Technology: