Navigation Links
Novel nano-structures to realize hydrogen's energy potential
Date:8/15/2012

For the first time, engineers at the University of New South Wales have demonstrated that hydrogen can be released and reabsorbed from a promising storage material, overcoming a major hurdle to its use as an alternative fuel source.

Researchers from the Materials Energy Research Laboratory in nanoscale (MERLin) at UNSW have synthesised nanoparticles of a commonly overlooked chemical compound called sodium borohydride (NaBH4) and encased these inside nickel shells. Their unique nanostructure has demonstrated remarkable hydrogen storage properties.

"No one has ever tried to synthesise these particles at the nanoscale because they thought it was too difficult, and couldn't be done. We're the first to do so, and demonstrate that energy in the form of hydrogen can be stored with sodium borohydride at practical temperatures and pressures," says Dr Kondo-Francois Aguey-Zinsou from the School of Chemical Engineering at UNSW.

Considered a major a fuel of the future, able to bridge the gap between renewables and fossil fuels, hydrogen could be used to power buildings, portable electronics and vehicles but this application hinges on practical storage technology.

Lightweight compounds known as borohydrides (including lithium and sodium compounds) are known to be effective storage materials but it was believed that once the energy was released it could not be reabsorbed a critical limitation. This perceived "irreversibility" means there has been little focus on sodium borohydride.

However, the UNSW result published in the journal ACS Nano, demonstrates for the first time that reversibility is indeed possible using a borohydride material by itself and could herald significant advances in the design of novel hydrogen storage materials.

"By controlling the size and architecture of these structures we can tune their properties and make them reversible this means they can release and reabsorb hydrogen," says Aguey-Zinsou, lead author on the paper. "We now have a way to tap into all these borohydride materials, which are particularly exciting for application on vehicles because of their high hydrogen storage capacity."

The researchers observed remarkable improvements in the thermodynamic and kinetic properties of their material. This means the chemical reactions needed to absorb and release hydrogen occurred faster than previously studied materials, and at significantly reduced temperatures making possible applications far more practical.

In its bulk form, sodium borohydride requires temperatures above 550 degrees Celsius just to release hydrogen. Even on the nano-scale the improvements are minimal.However, with their core-shell nanostructure, the researchers saw initial energy release happening at just 50 C, and significant release at 350 C.

"The new materials that could be generated by this exciting strategy could provide practical solutions to meet many of the energy targets set by the US Department of Energy," says Aguey-Zinsou. "The key thing here is that we've opened the doorway."


'/>"/>

Contact: Myles Gough
myles.gough@unsw.edu.au
61-029-385-1933
University of New South Wales
Source:Eurekalert

Related biology news :

1. Cleveland Clinic researchers receive $5 million grant to discover novel pathways to heart disease
2. VTT and GE Healthcare developing novel biomarkers to predict Alzheimers disease
3. Mexican rock heroes trial novel green trading system
4. London researchers discover novel mechanism involved in key immune response
5. Novel discovery by NUS scientists paves the way for more effective treatment of cancers
6. Key proteins newly discovered form and function may provide novel cancer treatment target
7. Unique adaptations to a symbiotic lifestyle reveal novel targets for aphid insecticides
8. Notre Dame researchers using novel method to combat malaria drug resistance
9. New clinical trial explores novel noninvasive colon cancer screening test
10. Researchers discover novel therapy for Crohns disease
11. A new energy source: Major advance made in generating electricity from wastewater
Post Your Comments:
*Name:
*Comment:
*Email:
(Date:4/13/2017)... According to a new market research report "Consumer IAM Market by Solution ... Authentication Type, Deployment Mode, Vertical, and Region - Global Forecast to 2022", ... 14.30 Billion in 2017 to USD 31.75 Billion by 2022, at a ... ... MarketsandMarkets Logo ...
(Date:4/11/2017)... , April 11, 2017 NXT-ID, ... security technology company, announces the appointment of independent Directors Mr. ... to its Board of Directors, furthering the company,s corporate ... ... NXT-ID, we look forward to their guidance and benefiting from ...
(Date:4/5/2017)... 4, 2017 KEY FINDINGS The ... at a CAGR of 25.76% during the forecast period ... primary factor for the growth of the stem cell ... MARKET INSIGHTS The global stem cell market ... and geography. The stem cell market of the product ...
Breaking Biology News(10 mins):
(Date:10/12/2017)... ... October 12, 2017 , ... ... the three Winners and six Finalists of the 2017 Blavatnik Regional Awards for ... Blavatnik Family Foundation and administered by the New York Academy of Sciences to ...
(Date:10/12/2017)... CA (PRWEB) , ... October ... ... (https://www.onramp.bio/ ) has launched Rosalind™, the first-ever genomics analysis platform specifically designed ... bioinformatics complexity. Named in honor of pioneering researcher Rosalind Franklin, who made ...
(Date:10/11/2017)... ... October 11, 2017 , ... Proscia Inc ... hosting a Webinar titled, “Pathology is going digital. Is your lab ready?” with ... adoption best practices and how Proscia improves lab economics and realizes an increase ...
(Date:10/11/2017)... ... October 11, 2017 , ... Singh Biotechnology today ... designation to SBT-100, its novel anti-STAT3 (Signal Transducer and Activator of Transcription 3) ... able to cross the cell membrane and bind intracellular STAT3 and inhibit its ...
Breaking Biology Technology: