Researchers at the National Institute of Standards and Technology (NIST) have developed a new computational method for identifying candidate refrigerant fluids with low "global warming potential" (GWP) the tendency to trap heat in the atmosphere for many decades as well as other desirable performance and safety features.
The NIST effort is the most extensive systematic search for a new class of refrigerants that meet the latest concerns about climate change. The new method was used to identify about 1,200 promising, low-GWP chemicals* for further study among some 56,000 that were considered. Only about 60 of these have boiling points low enough to be suitable for common refrigeration equipment, an indication of how difficult it is to identify usable fluids.
The ongoing NIST project is a response to U.S. industry interest in a new generation of alternative refrigerants that already are required for use in the European Union.
The refrigerants now used in cars and homes are mainly hydrofluorocarbons (HFCs). They were adopted a generation ago in the effort to phase out chlorofluorocarbons (CFCs), which deplete the stratospheric ozone layer. An example is R-134a (1,1,1,2-tetrafluoroethane), which replaced ozone-depleting chemicals in automobile air conditioners and home refrigerators. R-134a now is being phased out in Europe because HFCs remain in the atmosphere for many years, yielding a high GWP. A compound's GWP is defined as the warming potential of one kilogram of the gas relative to one kilogram of carbon dioxide. R-134a has a GWP of 1,430, much higher than the GWP of 150 or less now mandated for automotive use in Europe.
Promising low-GWP chemicals include fluorinated olefins, which react rapidly with atmospheric compounds and thus will not persist for long periods.
"What industry is trying to do is be prepared, because moving from a GWP in the thousands or tens of thousands to a GWP of 150 is an enormous challen
|Contact: Laura Ost|
National Institute of Standards and Technology (NIST)