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NASA researchers find clues to a secret of life
Date:3/17/2009

ing more left-handed isovaline in a variety of meteorites supports the theory that amino acids brought to the early Earth by asteroids and comets contributed to the origin of only left-handed based protein life on Earth," said Glavin.

All amino acids can switch from left-handed to right, or the reverse, by chemical reactions energized with radiation or temperature, according to the team. The scientists looked for isovaline because it has the ability to preserve its handedness for billions of years, and it is extremely rarely used by life, so its presence in meteorites is unlikely to be from contamination by terrestrial life. "The meteorites we studied are from before Earth formed, over 4.5 billion years ago," said Glavin. "We believe the same process that created extra left-handed isovaline would have created more left-handed versions of the other amino acids found in these meteorites, but the bias toward left-handed versions has been mostly erased after all this time."

The team's discovery validates and extends the research first reported a decade ago by Drs. John Cronin and Sandra Pizzarello of Arizona State University, who were first to discover excess isovaline in the Murchison meteorite, believed to be a piece of an asteroid. "We used a different technique to find the excess, and discovered it for the first time in the Orgueil meteorite, which belongs to another meteorite group believed to be from an extinct comet," said Glavin.

The team also found a pattern to the excess. Different types of meteorites had different amounts of water, as determined by the clays and water-bearing minerals found in the meteorites. The team discovered meteorites with more water also had greater amounts of left-handed isovaline. "This gives us a hint that the creation of extra left-handed amino acids had something to do with alteration by water," said Dworkin. "Since there are many ways to make extra left-handed amino acids, this discovery considerably nar
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Contact: Bill Steigerwald
william.a.steigerwald@nasa.gov
301-286-5017
NASA/Goddard Space Flight Center
Source:Eurekalert  

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