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LAMIS -- a green chemistry alternative for laser spectroscopy
Date:3/1/2012

ide or fluoride, and then collect the molecular light emissions."

Russo and his research group have been using LAMIS to study isotopes of strontium, an alkaline earth metal commonly found in geological and natural materials. Although strontium's major isotopes are stable (strontium-90 being a notable exception), the percentage of strontium-87 will naturally increase over time as a result of the decay of radioactive rubidium. Comparing the ratio of strontium-87 to strontium-86 is a standard tool for age dating in geochronology, oceanography and archeology. The ratio of these strontium isotopes is also used to date the origin of historic or forensic samples. Currently, the standard means of measuring strontium isotopic ratios is by mass spectrometry technologies that involve time-consuming, labor-intensive laboratory sample dissolution work with an extensive array of instrumentation. This sample dissolution work generates substantial chemical waste. LAMIS offers a green chemistry alternative that is faster, less expensive and can be carried out from across vast distances.

"LAMIS is not yet as sensitive or precise as mass spectrometry but unlike mass spectrometry it does not require chemical dissolution sample preparation, vacuum chambers and a laboratory infrastructure," Russo says. "All we need is a laser beam and an optical spectrometer and we can perform real-time isotopic analyses of samples at ambient pressures and temperatures."

LAMIS represents what may be the only practical means of determining the geochronology of samples on Mars or other celestial bodies in the Solar System. Current age estimates of such bodies suffer from uncertainties in the billions of years. That said, LAMIS also has many important applications here on Earth. Strontium isotope ratios have been a focus in the field of medicine for both treatment and diagnostic purposes. Measuring these ratios can also provide valuable information about atmospheric chemistry. The
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Contact: Lynn Yarris
lcyarris@lbl.gov
510-486-5375
DOE/Lawrence Berkeley National Laboratory
Source:Eurekalert  

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