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Duke scientists look deeper for coal ash hazards
Date:11/29/2010

DURHAM, N.C. As the U.S. Environmental Protection Agency weighs whether to define coal ash as hazardous waste, a Duke University study identifies new monitoring protocols and insights that can help investigators more accurately measure and predict the ecological impacts of coal ash contaminants.

"The take-away lesson is we need to change how and where we look for coal ash contaminants," says Avner Vengosh, professor of geochemistry and water quality at Duke's Nicholas School of the Environment. "Risks to water quality and aquatic life don't end with surface water contamination, but much of our current monitoring does."

The study, published online this week in the peer-reviewed journal Environmental Science and Technology, documents contaminant levels in aquatic ecosystems over an 18-month period following a massive coal sludge spill in 2008 at a Tennessee Valley Authority power plant in Kingston, Tenn.

By analyzing more than 220 water samples collected over the 18-month period, the Duke team found that high concentrations of arsenic from the TVA coal ash remained in pore water -- water trapped within river-bottom sediment -- long after contaminant levels in surface waters dropped back below safe thresholds. Samples extracted from 10 centimeters to half a meter below the surface of sediment in downstream rivers contained arsenic levels of up to 2,000 parts per billion well above the EPA's thresholds of 10 parts per billion for safe drinking water, and 150 parts per billion for protection of aquatic life.

"It's like cleaning your house," Vengosh says of the finding. "Everything may look clean, but if you look under the rugs, that's where you find the dirt."

The potential impacts of pore water contamination extend far beyond the river bottom, he explains, because "this is where the biological food chain begins, so any bioaccumulation of toxins will start here."

The research team, which included two gra
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Contact: Tim Lucas
tdlucas@duke.edu
919-613-8084
Duke University
Source:Eurekalert

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