Navigation Links
Breakthrough could lead to cheaper, more sustainable chemical production
Date:3/21/2013

PROVIDENCE, R.I. [Brown University] A key advance, newly reported by chemists from Brown and Yale Universities, could lead to a cheaper and more sustainable way to make acrylate, an important commodity chemical used to make materials from polyester fabrics to diapers.

Chemical companies churn out billions of tons of acrylate each year, usually by heating propylene, a compound derived from crude oil. "What we're interested in is enhancing both the economics and the sustainability of how acrylate is made," said Wesley Bernskoetter, assistant professor of chemistry at Brown, who led the research. "Right now, everything that goes into making it is from relatively expensive, nonrenewable carbon sources."

Since the 1980s researchers have been looking into the possibility of making acrylate by combining carbon dioxide with a gas called ethylene in the presence of nickel and other metal catalysts. CO2 is essentially free and something the planet currently has in overabundance. Ethylene is cheaper than propylene and can be made from plant biomass.

There has been a persistent obstacle to the approach, however. Instead of forming the acrylate molecule, CO2 and ethylene tend to form a precursor molecule with a five-membered ring made of oxygen, nickel, and three carbon atoms. In order to finish the conversion to acrylate, that ring needs to be cracked open to allow the formation of a carbon-carbon double bond, a process called elimination.

That step had proved elusive. But the research by Bernskoetter and his colleagues, published in the journal Organometallics, shows that a class of chemicals called Lewis acids can easily break open that five-membered ring, allowing the molecule to eliminate and form acrylate.

Lewis acids are basically electron acceptors. In this case, the acid steals away electrons that make up the bond between nickel and oxygen in the ring. That weakens the bond and opens the ring.

"We thought that if we could find a way to cut the ring chemically, then we would be able to eliminate very quickly and form acrylate," Bernskoetter said. "And that turns out to be true."

He calls the finding an "enabling technology" that could eventually be incorporated in a full catalytic process for making acrylate on a mass scale. "We can now basically do all the steps required," he said.

From here, the team needs to tweak the strength of the Lewis acid used. To prove the concept, they used the strongest acid that was easily available, one derived from boron. But that acid is too strong to use in a repeatable catalytic process because it bonds too strongly to the acrylate product to allow additional reactions with the nickel catalyst.

"In developing and testing the idea, we hit it with the biggest hammer we could," Bernskoetter said. "So what we have to do now is dial back and find one that makes it more practical."

There's quite a spectrum of Lewis acid strengths, so Bernskoetter is confident that there's one that will work. "We think it's possible," he said. "Organic chemists do this kind of reaction with Lewis acids all the time."

The ongoing research is part of a collaboration between Brown and Yale supported by the National Science Foundation's Centers for Chemical Innovation program. The work is aimed at activating CO2 for use in making all kinds of commodity chemicals, and acrylate is a good place to start.

"It's around a $2 billion-a-year industry," Bernskoetter said. "If we can find a way to make acrylate more cheaply, we think the industry will be interested."


'/>"/>

Contact: Kevin Stacey
kevin_stacey@brown.edu
401-863-3766
Brown University
Source:Eurekalert

Related biology news :

1. Nottingham technology in heart development breakthrough
2. Flu breakthrough: New drug developed to combat flu pandemic
3. Breakthrough study opens door to broader biomedical applications for Raman spectroscopy
4. Explosive breakthrough in research on molecular recognition
5. Stem cell breakthrough could lead to new bone repair therapies on nanoscale surfaces
6. A Spanish breakthrough allows the electroporation of cell cultures for less than 1 Euro
7. Recent breakthroughs in cocoa flavanol research discussed by European research consortium and expert panel
8. Breakthrough: How salt stops plant growth
9. Genetic sequencing breakthrough to aid treatment for congenital hyperinsulinism
10. Plant organ development breakthrough
11. USDA scientists and cooperators sequence the wheat genome in breakthrough for global food security
Post Your Comments:
*Name:
*Comment:
*Email:
(Date:2/27/2017)... , Feb. 27, 2017   Strategic Cyber Ventures ... it has led a $3.5 million investment in  Polarity ... Strategic Cyber Ventures is DC based and is led ... Hank Thomas . Ron Gula , also a ... also participated in this series A round of funding. ...
(Date:2/24/2017)... , Feb. 24, 2017  EyeLock LLC, a leader ... its elite iris biometric solution on the latest ... LTE at Mobile World Congress 2017 (February ... Booth in Hall 3, Stand 3E10. ... Qualcomm Haven™ security platform—a combination of hardware, ...
(Date:2/21/2017)... and PORTLAND, Ore. , ... and the Avamere Family of Companies (Avamere Health Services, ... announced a six-month research study that will apply the ... eldercare at senior living and health centers. By analyzing ... hopes to gain insights into physical and environmental conditions, ...
Breaking Biology News(10 mins):
(Date:3/22/2017)... 2017 Regeneron Pharmaceuticals, Inc. (NASDAQ: REGN), today announced ... U.K. Biobank and GSK to generate genetic sequence data from ... initiative will enable researchers to gain valuable insights to support ... range of serious and life threatening diseases. ... Genetic evidence has ...
(Date:3/22/2017)... 2017 Good Start Genetics, a leading family ... 130 million covered lives mark through its most recent ... Texas . With newly signed contracts nationally and ... strong payor acceptance based on the quality of its ... counseling, its industry-leading customer care and support and its ...
(Date:3/22/2017)... Florida , March 22, 2017 ... ... various cancer conditions are being pressured as of late due ... for cancer pain management has a dramatic impact on patient,s ... research and development activities for identifying new forms of opioid ...
(Date:3/22/2017)... ... ... Premier executive recruitment firm, Slone Partners, is proud to have been named a Top ... Hunt Scanlon Media is one of the most respected life science publications in the ... sector. , “It is a great honor for Slone Partners to be part of ...
Breaking Biology Technology: