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Better batteries through biology?
Date:11/13/2013

CAMBRIDGE, Mass. Lithium-air batteries have become a hot research area in recent years: They hold the promise of drastically increasing power per battery weight, which could lead, for example, to electric cars with a much greater driving range. But bringing that promise to reality has faced a number of challenges, including the need to develop better, more durable materials for the batteries' electrodes and improving the number of charging-discharging cycles the batteries can withstand.

Now, MIT researchers have found that adding genetically modified viruses to the production of nanowires wires that are about the width of a red blood cell, and which can serve as one of a battery's electrodes could help solve some of these problems.

The new work is described in a paper published in the journal Nature Communications, co-authored by graduate student Dahyun Oh, professors Angela Belcher and Yang Shao-Horn, and three others. The key to their work was to increase the surface area of the wire, thus increasing the area where electrochemical activity takes place during charging or discharging of the battery.

The researchers produced an array of nanowires, each about 80 nanometers across, using a genetically modified virus called M13, which can capture molecules of metals from water and bind them into structural shapes. In this case, wires of manganese oxide a "favorite material" for a lithium-air battery's cathode, Belcher says were actually made by the viruses. But unlike wires "grown" through conventional chemical methods, these virus-built nanowires have a rough, spiky surface, which dramatically increases their surface area.

Belcher, the W.M. Keck Professor of Energy and an affiliate of MIT's Koch Institute for Integrative Cancer Research, explains that this process of biosynthesis is "really similar to how an abalone grows its shell" in that case, by collecting calcium from seawater and depositing it into a solid, li
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Contact: Sarah McDonnell
s_mcd@mit.edu
617-253-8923
Massachusetts Institute of Technology
Source:Eurekalert

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