Navigation Links
24-carat gold 'snowflakes' improve graphene's electrical properties

In an effort to make graphene more useful in electronics applications, Kansas State University engineers made a golden discovery -- gold "snowflakes" on graphene.

Vikas Berry is a K-State assistant professor of chemical engineering who works with graphene, a carbon material only a single atom thick and discovered just five years ago. To functionalize graphene with gold -- thus controlling its electronics properties -- Berry and Kabeer Jasuja, a K-State doctoral student in chemical engineering, imbedded gold on graphene.

To do this, the engineers placed the graphene oxide sheets in a gold ion solution that had a growth catalyst. Here, the atomically thick sheets swim and bathe in a pool of chemicals.

"Graphene-derivatives act like swimming molecular carpets when in solution and exhibit fascinating physiochemical behavior," Berry said. "If we change the surface functionality or the concentration, we can control their properties."

They found that rather than distributing itself evenly over graphene, the gold formed islands on the sheets' surfaces. They named these islands snowflake-shaped gold nanostars, or SFGNs.

"So we started exploring how these gold nanostars are formed," Berry said. "We found out that nanostars with no surface functionality are rather challenging to produce by other chemical processes. We can control the size of these nanostars and have characterized the mechanism of nucleation and growth of these nanostructures. It's similar to the mechanism that forms real snowflakes."

Berry said the presence of graphene is critical for the formation of the gold nanostars. "If graphene is absent, the gold would clump together and settle down as big chunks," he said. "But the graphene helps in stabilizing the gold. This makes the nanostars more useful for electronic applications."

In July, Jasuja and Berry published their work in the journal ACS-Nano.

The discovery of these gold "snowflakes" on graphene shows promise for biological devices as well as electronics. Berry is attaching DNA to these gold islands to make DNA sensors. He is joined by Nihar Mohanty, a doctoral student in chemical engineering, and undergraduate researcher Ashvin Nagaraja, a senior in electrical engineering. Nagaraja is a 2004 Manhattan High School graduate.

Berry said graphene-gold based DNA sensors will have enhanced sensitivity. Chemically reducing graphene oxide to obtain graphene requires harsh chemicals that destroy the DNA.

"Now we can use the harsh chemicals on graphene oxide imbedded with gold to obtain graphene with gold islands. Then we can use these gold islands to functionalize DNA."

Berry also is using graphene in conjunction with microwaves. He and Jasuja are "cooking" the graphene sheets as another way to produce particles on the material's surface.

Some of Berry's other graphene research involves using the modified graphene sheets to compartmentalize a coagulating solution, thus stabilizing it. His group has recently used hydrides to reduce graphene oxide to produce reduced graphene oxide in the matter of a few seconds. The graphene produced in this way can remain stable in the solution for several days. Further results will shortly appear in the journal Small

Discovered only five years ago, graphene has captured the attention of a large number of researchers who are studying its exceptional electrical, mechanical and optical properties, Berry said. His research group is among the few studying the material's interfacial properties and biological applications.

"We're entering a new era," Berry said. "From the zero-dimensional or one-dimensional molecular or polymer solutions, we are now venturing into the two-dimensional graphene solutions, which have fascinating new properties."


Contact: Vikas Berry
Kansas State University

Related biology news :

1. LSU professors work to improve efficiency of ethanol fuel
2. Geron Demonstrates hESC-derived cardiomyocytes improve heart function after myocardial infarction
3. Drug could improve pregnancy outcomes in wider range of women with insulin resistance
4. Improved e-jet printing provides higher resolution and more versatility
5. MIT model could improve some drugs effectiveness
6. NIH awards UC $9 million grant to improve patient point-of-care technologies
7. In-vitro fertilization improved with 3-D/4-D-guided embryo transfer and new placement target
8. Stronger EPA leadership needed to improve water quality in Mississippi River
9. Exercise improves thinking, reduces diabetes risk in overweight children
10. Endobronchial valve significantly improves emphysema
11. Teamwork improves learning and career success
Post Your Comments:
Related Image:
24-carat gold 'snowflakes' improve graphene's electrical properties
(Date:11/17/2015)... Paris from 17 th until 19 ... from 17 th until 19 th November 2015. ... invented the first combined scanner in the world which scans ... now two different scanners were required: one for passports and ... the same surface. This innovation is an ideal solution for ...
(Date:11/17/2015)... 2015 Pressure BioSciences, Inc. (OTCQB: PBIO) ("PBI" ... sale of broadly enabling, pressure cycling technology ("PCT")-based sample ... announced it has received gross proceeds of $745,000 from ... (the "Offering"), increasing the total amount raised to date ... closings are expected in the near future. ...
(Date:11/12/2015)... Mass. , Nov. 12, 2015  Arxspan ... Institute of MIT and Harvard for use of ... discovery information management tools. The partnership will support ... both biological and chemical research information internally and ... will be used for managing the Institute,s electronic ...
Breaking Biology News(10 mins):
(Date:11/24/2015)... FAR HILLS, N.J. (PRWEB) , ... November 24, 2015 , ... ... University, as the recipient of the 2016 USGA Green Section Award. Presented annually since ... of golf through his or her work with turfgrass. , Clarke, of ...
(Date:11/24/2015)... (PRWEB) , ... November 24, 2015 , ... ... maintain healthy metabolism. But unless it is bound to proteins, copper is also ... Health (NIH), researchers at Worcester Polytechnic Institute (WPI) will conduct a systematic study ...
(Date:11/24/2015)... India , November 24, 2015 ... a new market research report "Oligonucleotide Synthesis Market by ... Application (PCR, Gene Synthesis, Diagnostic, DNA, RNAi), End-User (Research, ... 2020", published by MarketsandMarkets, the market is expected to ... Million in 2015, at a CAGR of 10.1% during ...
(Date:11/24/2015)... 2015 --> ... released by Transparency Market Research, the global non-invasive prenatal ... of 17.5% during the period between 2014 and 2022. ... Industry Analysis, Size, Volume, Share, Growth, Trends and Forecast ... market to reach a valuation of US$2.38 bn by ...
Breaking Biology Technology: